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<\/p>\n<p>\u5e02\u9762\u4e0a\u5e38\u89c1\u7845\u6cb9\uff08\u5982\u7532\u57fa\u7845\u6cb9\u3001\u82ef\u57fa\u7845\u6cb9\uff09\u591a\u7528\u4e8e\u6da6\u6ed1\u6cb9\u3001\u5316\u5986\u54c1\u6216\u6d88\u6ce1\u5242\uff0c\u5176\u5206\u5b50\u91cf\u5206\u5e03\u5bbd\uff08Mw\/Mn &gt; 2.0\uff09\u3001\u7aef\u57fa\u672a\u5c01\u7aef\u3001\u6742\u8d28\u542b\u91cf\u9ad8\uff08\u6325\u53d1\u5206&gt;0.5%\uff09\uff0c\u76f4\u63a5\u6dfb\u52a0\u81f3PU\u4f53\u7cfb\u5c06\u5f15\u53d1\u4e25\u91cd\u540e\u679c\uff1a\u964d\u4f4e\u90b5\u6c0f\u786c\u5ea6\u3001\u524a\u5f31\u62c9\u4f38\u5f3a\u5ea6\u3001\u9020\u6210\u55b7\u971c\uff08\u8868\u9762\u6790\u51fa\u6cb9\u819c\uff09\u3001\u751a\u81f3\u5e72\u6270\u5f02\u6c30\u9178\u916f\u4e0e\u7f9f\u57fa\u7684\u50ac\u5316\u53cd\u5e94\u3002  <\/p>\n<p>\u800c3C\u7535\u5b50\u4e13\u7528\u7845\u6cb9\u662f\u7ecf\u8fc7\u56db\u91cd\u7cbe\u5bc6\u8bbe\u8ba1\u7684\u7279\u79cd\u6709\u673a\u7845\uff1a  <\/p>\n<ol>\n<li>\n<p>\u5206\u5b50\u91cf\u7cbe\u51c6\u63a7\u5236\uff1a\u91c7\u7528\u9634\u79bb\u5b50\u5f00\u73af\u805a\u5408\u5de5\u827a\uff0c\u4e25\u683c\u9650\u5b9a\u91cd\u5747\u5206\u5b50\u91cf\uff08Mw\uff09\u57288000\u201315000 g\/mol\u533a\u95f4\uff0c\u591a\u5206\u6563\u7cfb\u6570\uff08Mw\/Mn\uff09\u22641.15\u3002\u6b64\u8303\u56f4\u65e2\u4fdd\u8bc1\u8db3\u591f\u94fe\u957f\u4ee5\u951a\u5b9aPU\u8f6f\u6bb5\uff0c\u53c8\u907f\u514d\u5206\u5b50\u94fe\u8fc7\u957f\u5bfc\u81f4\u8fc1\u79fb\u901f\u7387\u52a0\u5feb\u3002\n<\/li>\n<li>\n<p>\u7aef\u57fa\u529f\u80fd\u5316\u4fee\u9970\uff1a\u4e24\u7aef\u4ee5\u7845\u7f9f\u57fa\uff08Si\u2013OH\uff09\u6216\u70f7\u6c27\u57fa\uff08Si\u2013OR\uff09\u5c01\u7aef\uff0c\u800c\u975e\u4f20\u7edf\u7532\u57fa\u5c01\u7aef\u3002\u8fd9\u4e9b\u6d3b\u6027\u7aef\u57fa\u53ef\u5728PU\u56fa\u5316\u5347\u6e29\u9636\u6bb5\uff0880\u2013120\u2103\uff09\u4e0ePU\u5206\u5b50\u94fe\u4e0a\u7684\u6b8b\u7559\u7f9f\u57fa\u6216\u6c28\u57fa\u53d1\u751f\u6e29\u548c\u7f29\u5408\uff0c\u5f62\u6210Si\u2013O\u2013C\u5171\u4ef7\u952e\u6865\u8fde\uff0c\u5b9e\u73b0\u7845\u6cb9\u4e0ePU\u57fa\u4f53\u7684\u201c\u5316\u5b66\u94c6\u63a5\u201d\uff0c\u675c\u7edd\u6e38\u79bb\u8fc1\u79fb\u3002\n<\/li>\n<li>\n<p>\u4e3b\u94fe\u7ed3\u6784\u5b9a\u5236\uff1a\u4e3b\u94fe\u975e\u7eaf\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\uff08PDMS\uff09\uff0c\u800c\u662f\u5f15\u516515\u201325 mol% \u7684\u82ef\u57fa\u7845\u6c27\u70f7\u5355\u5143\uff08PhMeSiO\uff09\u53ca3\u20138 mol% \u7684\u73af\u6c27\u4e19\u57fa\u7845\u6c27\u70f7\u5355\u5143\uff08GlycidoxypropylMe\u2082SiO\uff09\u3002\u82ef\u57fa\u63d0\u5347\u8010\u70ed\u6027\u4e0e\u6298\u5c04\u7387\u5339\u914d\u6027\uff08\u907f\u514d\u5149\u5b66\u90e8\u4ef6\u96fe\u5316\uff09\uff0c\u73af\u6c27\u57fa\u5219\u63d0\u4f9b\u989d\u5916\u4ea4\u8054\u4f4d\u70b9\uff0c\u589e\u5f3a\u9ad8\u6e29\u4e0b\u7f51\u7edc\u7a33\u5b9a\u6027\u3002  <\/p>\n<p><img decoding=\"async\" src=\"\/images\/57.jpg\" alt=\"\u4e13\u4e1a\u7ea7\u805a\u6c28\u916f3C\u7535\u5b50\u5bc6\u5c01\u51cf\u9707\u57ab\u4e13\u7528\u7845\u6cb9\uff0c\u63d0\u5347\u6750\u6599\u5728\u9ad8\u9891\u632f\u52a8\u73af\u5883\u4e0b\u7684\u7ed3\u6784\u5b8c\u6574\"><\/p>\n<\/li>\n<li>\n<p>\u8d85\u9ad8\u7eaf\u5ea6\u4fdd\u969c\uff1a\u7ecf\u4e09\u7ea7\u5206\u5b50\u84b8\u998f\u4e0e\u91d1\u5c5e\u7edc\u5408\u5438\u9644\u7eaf\u5316\uff0c\u94c1\u3001\u94dc\u3001\u954d\u7b49\u50ac\u5316\u6027\u91d1\u5c5e\u6b8b\u7559\uff1c5 ppm\uff0c\u6325\u53d1\u5206\uff1c0.05%\uff0c\u6c34\u5206\uff1c10 ppm\u3002\u8fd9\u5bf9\u9632\u6b62PU\u56fa\u5316\u540e\u671f\u4ea7\u751f\u6c14\u6ce1\u3001\u4fdd\u969c\u7535\u5b50\u5143\u4ef6\u957f\u671f\u53ef\u9760\u6027\u81f3\u5173\u91cd\u8981\u3002\n<\/li>\n<\/ol>\n<p>\u7b80\u8a00\u4e4b\uff0c\u8be5\u7845\u6cb9\u7684\u672c\u8d28\u662f\u201c\u5177\u6709PU\u4eb2\u548c\u6027\u7684\u6709\u673a\u7845\u5927\u5206\u5b50\u5076\u8054\u5242\u201d\uff0c\u5176\u4f5c\u7528\u5df2\u8d85\u8d8a\u4f20\u7edf\u52a9\u5242\u8303\u7574\uff0c\u6210\u4e3aPU\u914d\u65b9\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u7b2c\u56db\u7ec4\u5206\u201d\u3002<\/p>\n<p>\u56db\u3001\u4f5c\u7528\u673a\u7406\uff1a\u4e09\u91cd\u534f\u540c\u6548\u5e94\u89e3\u6790  <\/p>\n<p>\u4e13\u7528\u7845\u6cb9\u5bf9PU\u51cf\u9707\u57ab\u7684\u6027\u80fd\u63d0\u5347\uff0c\u5e76\u975e\u5355\u4e00\u7ef4\u5ea6\u6539\u5584\uff0c\u800c\u662f\u901a\u8fc7\u4ee5\u4e0b\u4e09\u91cd\u7269\u7406\u5316\u5b66\u673a\u5236\u534f\u540c\u5b9e\u73b0\uff1a  <\/p>\n<p>\uff08\u4e00\uff09\u8f6f\u6bb5\u5851\u5316\u4e0e\u52a8\u6001\u677e\u5f1b\u52a0\u901f<br \/>\n\u7845\u6cb9\u5206\u5b50\u5d4c\u5165PU\u8f6f\u6bb5\u5bcc\u96c6\u533a\uff0c\u5176\u67d4\u6027\u7845\u6c27\u94fe\uff08Si\u2013O\u952e\u80fd377 kJ\/mol\uff0c\u8fdc\u4f4e\u4e8eC\u2013C\u952e\u7684347 kJ\/mol\uff09\u663e\u8457\u964d\u4f4e\u8f6f\u6bb5\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg\uff09\u5c40\u90e8\u6ce2\u52a8\u5e45\u5ea6\u3002DSC\u6d4b\u8bd5\u663e\u793a\uff1a\u6dfb\u52a01.2 wt%\u4e13\u7528\u7845\u6cb9\u540e\uff0cPU\u8f6f\u6bb5Tg\u5cf0\u5bbd\uff08\u0394Tg\uff09\u753118.5\u2103\u6536\u7a84\u81f39.3\u2103\uff0c\u8868\u660e\u94fe\u6bb5\u8fd0\u52a8\u5747\u4e00\u6027\u63d0\u5347\u3002\u8fd9\u4f7f\u6750\u6599\u5728\u9ad8\u9891\u632f\u52a8\u4e0b\u80fd\u66f4\u53ca\u65f6\u54cd\u5e94\u5e94\u529b\u53d8\u5316\uff0c\u51cf\u5c11\u80fd\u91cf\u6ede\u7559\uff0c\u4ece\u800c\u964d\u4f4etan\u03b4\u5cf0\u503c\u6e29\u5ea6\uff0c\u5ef6\u7f13\u70ed\u79ef\u7d2f\u3002  <\/p>\n<p>\uff08\u4e8c\uff09\u786c\u6bb5\u5fae\u533a\u754c\u9762\u5f3a\u5316<br \/>\n\u7845\u6cb9\u4e2d\u82ef\u57fa\u4e0ePU\u786c\u6bb5\u82b3\u73af\u5b58\u5728\u03c0\u2013\u03c0\u5f31\u76f8\u4e92\u4f5c\u7528\uff0c\u73af\u6c27\u57fa\u5219\u53ef\u4e0e\u786c\u6bb5\u672b\u7aef\u6c28\u57fa\u53d1\u751f\u5f00\u73af\u52a0\u6210\u3002\u4e8c\u8005\u5171\u540c\u4f5c\u7528\uff0c\u4f7f\u786c\u6bb5\u5fae\u533a\u4e0e\u5468\u56f4\u8f6f\u6bb5\u7684\u754c\u9762\u8fc7\u6e21\u5c42\u539a\u5ea6\u589e\u52a0\u7ea62\u20133 nm\uff0c\u754c\u9762\u7ed3\u5408\u80fd\u63d0\u5347\u7ea640%\u3002\u8fd9\u6781\u5927\u6291\u5236\u4e86\u9ad8\u9891\u526a\u5207\u4e0b\u786c\u6bb5\u7c07\u7684\u5f02\u5e38\u805a\u96c6\u4e0e\u89e3\u79bb\uff0c\u7ef4\u6301\u76f8\u5206\u79bb\u5c3a\u5ea6\u7a33\u5b9a\u3002SAXS\uff08\u5c0f\u89d2X\u5c04\u7ebf\u6563\u5c04\uff09\u8bc1\u5b9e\uff1a\u542b\u4e13\u7528\u7845\u6cb9\u7684PU\u6837\u54c1\u57283000 Hz\u632f\u52a8100\u5c0f\u65f6\u540e\uff0c\u786c\u6bb5\u76f8\u5173\u5cf0\u4f4d\u7f6e\u504f\u79fb\uff1c0.8%\uff0c\u800c\u5bf9\u7167\u6837\u504f\u79fb\u8fbe3.2%\u3002  <\/p>\n<p>\uff08\u4e09\uff09\u57fa\u6750\u754c\u9762\u80fd\u68af\u5ea6\u6784\u5efa<br \/>\n\u7845\u6cb9\u5206\u5b50\u5728PU\u56fa\u5316\u8fc7\u7a0b\u4e2d\u5b9a\u5411\u8fc1\u79fb\u81f3\u6750\u6599\u8868\u9762\uff0c\u5176\u4f4e\u8868\u9762\u80fd\uff0820\u201322 mN\/m\uff09\u4e0ePU\u672c\u4f53\uff0838\u201342 mN\/m\uff09\u5f62\u6210\u68af\u5ea6\u8fc7\u6e21\u5c42\u3002\u8be5\u5c42\u65e2\u4e0d\u8fc7\u5ea6\u964d\u4f4e\u8868\u9762\u80fd\u81f4\u9644\u7740\u529b\u4e0b\u964d\uff0c\u53c8\u80fd\u6709\u6548\u7f13\u89e3\u4e0d\u540c\u70ed\u81a8\u80c0\u7cfb\u6570\uff08CTE\uff09\u6750\u6599\u95f4\u7684\u70ed\u5e94\u529b\u3002\u4f8b\u5982\uff0cPU\u57ab\uff08CTE\u2248120 ppm\/K\uff09\u4e0e\u94dd\u5408\u91d1\u4e2d\u6846\uff08CTE\u224823 ppm\/K\uff09\u5728-20\u2103\u81f360\u2103\u5faa\u73af\u4e2d\uff0c\u754c\u9762\u526a\u5207\u5e94\u529b\u5cf0\u503c\u53ef\u964d\u4f4e35%\u3002  <\/p>\n<p>\u4e94\u3001\u5173\u952e\u6027\u80fd\u53c2\u6570\u4e0e\u9009\u578b\u903b\u8f91\uff08\u8868\u683c\u8bf4\u660e\uff09  <\/p>\n<p>\u4e0b\u8868\u5217\u51fa\u4e86\u5f53\u524d\u4e3b\u6d41\u4f9b\u5e94\u5546\u63d0\u4f9b\u7684\u4e13\u4e1a\u7ea7\u7845\u6cb9\u5178\u578b\u6280\u672f\u6307\u6807\u3002\u9700\u5f3a\u8c03\uff1a\u53c2\u6570\u9009\u62e9\u7edd\u975e\u201c\u8d8a\u9ad8\u8d8a\u597d\u201d\uff0c\u800c\u987b\u5339\u914d\u5177\u4f53PU\u914d\u65b9\u4e0e\u7ec8\u7aef\u9700\u6c42\u3002  <\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u7c7b\u522b<\/th>\n<th>\u6307\u6807\u540d\u79f0<\/th>\n<th>\u5178\u578b\u6570\u503c\u8303\u56f4<\/th>\n<th>\u5de5\u7a0b\u610f\u4e49\u4e0e\u9009\u578b\u63d0\u793a<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u57fa\u7840\u7269\u6027<\/td>\n<td>25\u2103\u8fd0\u52a8\u7c98\u5ea6\uff08cSt\uff09<\/td>\n<td>8000\u201312000<\/td>\n<td>\u7c98\u5ea6\u8fc7\u4f4e\uff08\uff1c5000 cSt\uff09\u6613\u8fc1\u79fb\uff1b\u8fc7\u9ad8\uff08\uff1e15000 cSt\uff09\u6df7\u70bc\u5206\u6563\u56f0\u96be\uff0c\u9700\u5ef6\u957f\u771f\u7a7a\u8131\u6ce1\u65f6\u95f4\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u6298\u5c04\u7387\uff0825\u2103, 589 nm\uff09<\/td>\n<td>1.425\u20131.438<\/td>\n<td>\u4e0e\u5e38\u7528PU\u6811\u8102\uff081.432\u20131.440\uff09\u5339\u914d\uff0c\u907f\u514d\u5149\u5b66\u90e8\u4ef6\u5468\u8fb9\u51fa\u73b0\u8679\u5f69\u5e72\u6d89\u6761\u7eb9\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u5316\u5b66\u7ed3\u6784<\/td>\n<td>\u82ef\u57fa\u542b\u91cf\uff08mol%\uff09<\/td>\n<td>18\u201322<\/td>\n<td>\uff1c15%\u8010\u70ed\u4e0d\u8db3\uff1b\uff1e25%\u4f4e\u6e29\u8106\u6027\u4e0a\u5347\uff0c-30\u2103\u4e0b\u90b5\u6c0fA\u786c\u5ea6\u589e\u5e45\u8d8515\u70b9\uff0c\u5f71\u54cd\u6781\u5bd2\u73af\u5883\u56de\u5f39\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u73af\u6c27\u503c\uff08mol\/100g\uff09<\/td>\n<td>0.12\u20130.18<\/td>\n<td>\u8fc7\u9ad8\uff08\uff1e0.20\uff09\u6613\u5bfc\u81f4PU\u56fa\u5316\u901f\u7387\u5f02\u5e38\u52a0\u5feb\uff0c\u4ea7\u751f\u5185\u5e94\u529b\uff1b\u8fc7\u4f4e\uff08\uff1c0.08\uff09\u754c\u9762\u5f3a\u5316\u6548\u679c\u4e0d\u8db3\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u7eaf\u5ea6\u4e0e\u7a33\u5b9a\u6027<\/td>\n<td>\u6325\u53d1\u5206\uff08150\u2103, 2h, wt%\uff09<\/td>\n<td>\u22640.05<\/td>\n<td>\u76f4\u63a5\u5173\u8054\u6210\u54c1VOC\u91ca\u653e\u91cf\uff0c\u6b27\u76dfRoHS\u4e0eIEC 62474\u8981\u6c42\uff1c0.1%\uff0c\u82f9\u679cApple QP\u8981\u6c42\uff1c0.03%\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u94c1\uff08Fe\uff09\u542b\u91cf\uff08ppm\uff09<\/td>\n<td>\u22643<\/td>\n<td>Fe\u00b2\u207a\/Fe\u00b3\u207a\u662fPU\u6c27\u5316\u964d\u89e3\u5f3a\u50ac\u5316\u5242\uff0c\uff1e5 ppm\u65f6\uff0c85\u2103\/85%RH\u8001\u53161000h\u540e\u65ad\u88c2\u4f38\u957f\u7387\u4fdd\u6301\u7387\u4e0b\u964d\u8d8525%\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u6c34\u5206\uff08Karl Fischer, ppm\uff09<\/td>\n<td>\u22648<\/td>\n<td>\u6c34\u5206\u4e0e\u5f02\u6c30\u9178\u916f\u53cd\u5e94\u751f\u6210CO\u2082\uff0c\u5bfc\u81f4\u5fae\u5b54\u7f3a\u9677\uff1b\uff1e15 ppm\u65f6\uff0c\u771f\u7a7a\u6d47\u6ce8\u4ef6\u6c14\u6ce1\u7387\u589e\u52a03\u500d\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u5e94\u7528\u6027\u80fd<\/td>\n<td>\u76f8\u5bb9\u6027\uff08PU\u4f53\u7cfb\uff09<\/td>\n<td>\u5b8c\u5168\u900f\u660e\uff0c\u65e0\u6790\u51fa<\/td>\n<td>\u6d4b\u8bd5\u6cd5\uff1a\u63091.0 wt%\u6dfb\u52a0\u81f3\u9884\u805a\u4f53\uff0c80\u2103\u6405\u62cc30min\uff0c\u51b7\u5374\u81f325\u2103\u9759\u7f6e72h\uff0c\u76ee\u89c6\u89c2\u5bdf\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u8fc1\u79fb\u6027\uff0860\u2103, 168h\uff09<\/td>\n<td>\u8868\u9762\u6cb9\u6591\u76f4\u5f84\u22640.3 mm<\/td>\n<td>\u52a0\u901f\u8001\u5316\u6cd5\uff1a\u6d82\u8986\u4e8e\u73bb\u7483\u677f\uff0c\u8986PET\u819c\u538b\u5408\uff0c60\u2103\u70d8\u7bb1\u653e\u7f6e7\u5929\uff0c\u6d4b\u91cf\u6e17\u51fa\u6cb9\u6655\u76f4\u5f84\u3002<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u9ad8\u9891\u963b\u5c3c\u63d0\u5347\u7387\uff083000Hz\uff09<\/td>\n<td>tan\u03b4\u5cf0\u503c\u63d0\u534718\u201325%<\/td>\n<td>\u4f9d\u636eISO 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