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-40\u2103\u81f385\u2103\u8303\u56f4\u5185\u538b\u7f29\u529b\u8870\u51cf\u7387\uff1c15%<br \/>\n\u2022 10\u2076\u6b21\u52a8\u6001\u538b\u7f29\u5faa\u73af\u540e\u56de\u5f39\u7387\u4fdd\u6301\uff1e92%  <\/p>\n<p>\u8981\u540c\u65f6\u6ee1\u8db3\u4e0a\u8ff0\u8981\u6c42\uff0c\u4ec5\u9760\u8c03\u6574\u591a\u5143\u9187\u79cd\u7c7b\u3001\u5f02\u6c30\u9178\u916f\u6307\u6570\uff08NCO\/OH\u6bd4\uff09\u6216\u6dfb\u52a0\u666e\u901a\u7269\u7406\u53d1\u6ce1\u5242\uff08\u5982\u6c34\uff09\u8fdc\u8fdc\u4e0d\u591f\u3002\u6b64\u65f6\uff0c\u4e13\u7528\u7845\u6cb9\u53d1\u6325\u56db\u5927\u4e0d\u53ef\u66ff\u4ee3\u4f5c\u7528\uff1a<\/p>\n<ol>\n<li>\n<p>\u6ce1\u5b54\u7ed3\u6784\u7cbe\u7ec6\u5316\u8c03\u63a7<br \/>\nPU\u51cf\u9707\u57ab\u591a\u4e3a\u5fae\u5b54\u5f39\u6027\u4f53\uff08\u5e73\u5747\u6ce1\u5b54\u76f4\u5f845\u201330 \u03bcm\uff09\uff0c\u975e\u81f4\u5bc6\u5b9e\u5fc3\u7ed3\u6784\u3002\u4e13\u7528\u7845\u6cb9\u51ed\u501f\u6781\u4f4e\u8868\u9762\u5f20\u529b\uff08\u901a\u5e3820\u201322 mN\/m\uff0c\u4f4e\u4e8ePU\u9884\u805a\u4f53\u4f53\u7cfb\u7ea635\u201340 mN\/m\uff09\uff0c\u663e\u8457\u964d\u4f4e\u6c14\u6db2\u754c\u9762\u80fd\uff0c\u4fc3\u8fdb\u6c2e\u6c14\/\u4e8c\u6c27\u5316\u78b3\u5fae\u6c14\u6ce1\u5747\u5300\u5f62\u6838\uff1b\u5176\u5206\u5b50\u94fe\u6bb5\u4e2d\u7684\u6781\u6027\u57fa\u56e2\u53ef\u5b9a\u5411\u5438\u9644\u4e8ePU\u8f6f\u786c\u6bb5\u754c\u9762\uff0c\u6291\u5236\u6ce1\u5b54\u5408\u5e76\uff08coalescence\uff09\uff0c\u4ece\u800c\u83b7\u5f97\u95ed\u5b54\u7387\uff1e95%\u3001\u5b54\u5f84\u5206\u5e03\u7cfb\u6570\uff08PDI\uff09\uff1c1.3\u7684\u5747\u4e00\u5fae\u5b54\u7ed3\u6784\u2014\u2014\u8fd9\u662f\u5b9e\u73b0\u4f4e\u538b\u7f29\u6c38\u4e45\u53d8\u5f62\u4e0e\u9ad8\u56de\u5f39\u7684\u57fa\u7840\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/20.jpg\" alt=\"\u805a\u6c28\u916f3C\u7535\u5b50\u5bc6\u5c01\u51cf\u9707\u57ab\u4e13\u7528\u7845\u6cb9\uff0c\u662f\u73b0\u4ee3\u7cbe\u5bc6\u7535\u5b50\u5bc6\u5c01\u65b9\u6848\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u52a9\u5242\"><\/p>\n<\/li>\n<li>\n<p>\u76f8\u5206\u79bb\u7a0b\u5ea6\u4f18\u5316<br \/>\n\u805a\u6c28\u916f\u672c\u8d28\u4e0a\u662f\u201c\u786c\u6bb5\uff08\u8132\/\u6c28\u57fa\u7532\u9178\u916f\u7ed3\u6676\u533a\uff09+\u8f6f\u6bb5\uff08\u805a\u919a\/\u805a\u916f\u65e0\u5b9a\u5f62\u533a\uff09\u201d\u7684\u5fae\u76f8\u5206\u79bb\u4f53\u7cfb\u3002\u76f8\u5206\u79bb\u8d8a\u5b8c\u5584\uff0c\u6750\u6599\u521a\u6027\u4e0e\u5f39\u6027\u8d8a\u534f\u540c\u3002\u4e13\u7528\u7845\u6cb9\u4e2d\u7684\u805a\u919a\u5d4c\u6bb5\u53ef\u63d2\u5165\u8f6f\u6bb5\u65e0\u5b9a\u5f62\u533a\uff0c\u524a\u5f31\u8f6f\u6bb5\u94fe\u95f4\u7f20\u7ed3\uff1b\u800c\u7845\u6c27\u70f7\u4e3b\u94fe\u5219\u503e\u5411\u4e8e\u5bcc\u96c6\u4e8e\u786c\u6bb5\u5fae\u533a\u8fb9\u7f18\uff0c\u5f62\u6210\u201c\u67d4\u6027\u754c\u9762\u5c42\u201d\uff0c\u65e2\u4fc3\u8fdb\u786c\u6bb5\u6709\u5e8f\u805a\u96c6\uff0c\u53c8\u907f\u514d\u8fc7\u5ea6\u7ed3\u6676\u5bfc\u81f4\u6750\u6599\u53d8\u8106\u3002\u5b9e\u9a8c\u8868\u660e\uff0c\u6dfb\u52a00.3\u20130.8 phr\uff08\u6bcf\u767e\u4efd\u6811\u8102\uff09\u4e13\u7528\u7845\u6cb9\uff0c\u53ef\u4f7f\u786c\u6bb5\u7ed3\u6676\u5ea6\u63d0\u534712\u201318%\uff0c\u800c\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg\uff09\u8f6f\u6bb5\u5e73\u53f0\u533a\u5bbd\u5ea6\u6536\u7a84\uff0c\u52a8\u6001\u529b\u5b66\u6027\u80fd\u66f4\u7a33\u5b9a\u3002\n<\/li>\n<li>\n<p>\u6a21\u5177\u754c\u9762\u6da6\u6e7f\u4e0e\u8131\u6a21\u5e73\u8861<br \/>\n3C\u7535\u5b50\u57ab\u7247\u5e38\u91c7\u7528\u7cbe\u5bc6\u91d1\u5c5e\u6a21\u5177\uff08\u516c\u5dee\u00b15 \u03bcm\uff09\u8fdb\u884c\u4f4e\u538b\u704c\u6ce8\u6216\u6a21\u538b\u6210\u578b\u3002\u82e5\u6da6\u6e7f\u6027\u8fc7\u5f3a\uff0c\u7845\u6cb9\u6613\u8fc1\u79fb\u5230\u5236\u54c1\u8868\u9762\uff0c\u9020\u6210\u540e\u7eed\u70b9\u80f6\u3001\u55b7\u6d82\u9644\u7740\u529b\u4e0b\u964d\uff1b\u82e5\u6da6\u6e7f\u6027\u8fc7\u5f31\uff0c\u5219\u586b\u5145\u4e0d\u6ee1\u3001\u8fb9\u89d2\u7f3a\u6599\u3002\u4e13\u7528\u7845\u6cb9\u901a\u8fc7\u8c03\u8282EO\/PO\u6bd4\u4f8b\uff08\u5e38\u7528EO:PO = 3:7\u81f31:1\uff09\u4e0e\u5206\u5b50\u91cf\uff08Mn = 3000\u20138000 g\/mol\uff09\uff0c\u4f7f\u5176\u5728110\u2013130\u2103\u52a0\u5de5\u6e29\u5ea6\u4e0b\u5177\u5907\u6070\u5230\u597d\u5904\u7684\u63a5\u89e6\u89d2\uff08\u6a21\u5177\u94a2\u8868\u9762\u7ea645\u00b0\u201355\u00b0\uff09\uff0c\u786e\u4fdd\u7194\u4f53\u5b8c\u5168\u590d\u5236\u5fae\u7ed3\u6784\uff0c\u53c8\u5728\u51b7\u5374\u540e\u63d0\u4f9b\u9002\u5ea6\u5185\u8131\u6a21\u529b\uff0c\u907f\u514d\u9876\u51fa\u635f\u4f24\u3002\n<\/li>\n<li>\n<p>\u957f\u671f\u670d\u5f79\u7a33\u5b9a\u6027\u5f3a\u5316<br \/>\n\u7535\u5b50\u8bbe\u5907\u751f\u547d\u5468\u671f\u666e\u904d\u8981\u6c425\u5e74\u4ee5\u4e0a\u3002\u666e\u901a\u7845\u6cb9\u5728\u9ad8\u6e29\u9ad8\u6e7f\u73af\u5883\u4e0b\u6613\u53d1\u751f\u6c27\u5316\u65ad\u94fe\uff0c\u751f\u6210\u4f4e\u5206\u5b50\u73af\u7845\u6c27\u70f7\uff08\u5982D4\uff09\uff0c\u540e\u8005\u5177\u6709\u8fc1\u79fb\u6027\uff0c\u53ef\u80fd\u6c61\u67d3\u90bb\u8fd1\u5149\u5b66\u955c\u5934\u6216\u7535\u5bb9\u5f0f\u89e6\u6478\u4f20\u611f\u5668\u3002\u4e13\u7528\u7845\u6cb9\u91c7\u7528\u9ad8\u7eaf\u5ea6\u516b\u7532\u57fa\u73af\u56db\u7845\u6c27\u70f7\uff08D4\uff09\u4e3a\u5355\u4f53\uff0c\u7ecf\u78b1\u50ac\u5316\u5f00\u73af\u805a\u5408\u540e\uff0c\u4e25\u683c\u63a7\u5236\u6b8b\u7559\u50ac\u5316\u5242\uff08KOH\uff1c1 ppm\uff09\uff0c\u5e76\u6dfb\u52a0\u53d7\u963b\u915a\u7c7b\u4e0e\u4e9a\u78f7\u9178\u916f\u7c7b\u590d\u5408\u7a33\u5b9a\u5242\uff0c\u4f7f\u70ed\u5931\u91cd\u8d77\u59cb\u6e29\u5ea6\uff08TGA 5% weight loss\uff09\u8fbe320\u2103\u4ee5\u4e0a\uff0c85\u2103\/85%RH\u52a0\u901f\u8001\u53161000\u5c0f\u65f6\u540e\uff0cD4\u6790\u51fa\u91cf\uff1c50 ppm\uff0c\u8fdc\u4f18\u4e8e\u901a\u7528\u578b\u53f7\u7684\uff1e500 ppm\u3002\n<\/li>\n<\/ol>\n<p>\u4e09\u3001\u5982\u4f55\u79d1\u5b66\u9009\u578b\uff1f\u5173\u952e\u53c2\u6570\u5bf9\u7167\u8868\u4e0e\u5e94\u7528\u6307\u5357<\/p>\n<p>\u9009\u578b\u4e0d\u662f\u770b\u201c\u7c98\u5ea6\u8d8a\u5927\u8d8a\u597d\u201d\u6216\u201c\u4ef7\u683c\u8d8a\u4f4e\u8d8a\u5212\u7b97\u201d\uff0c\u800c\u662f\u57fa\u4e8e\u5177\u4f53\u914d\u65b9\u4f53\u7cfb\u4e0e\u5de5\u827a\u7a97\u53e3\u5339\u914d\u3002\u4e0b\u8868\u5217\u51fa\u4e86\u4e3b\u6d41\u4f9b\u5e94\u5546\u63d0\u4f9b\u76846\u6b3e\u5178\u578b\u4e13\u7528\u7845\u6cb9\u6838\u5fc3\u53c2\u6570\uff0c\u5e76\u6807\u6ce8\u5176\u9002\u7528\u573a\u666f\u5efa\u8bae\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u9879<\/th>\n<th>\u578b\u53f7A<\/th>\n<th>\u578b\u53f7B<\/th>\n<th>\u578b\u53f7C<\/th>\n<th>\u578b\u53f7D<\/th>\n<th>\u578b\u53f7E<\/th>\n<th>\u578b\u53f7F<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>25\u2103\u8fd0\u52a8\u7c98\u5ea6 (cSt)<\/td>\n<td>120<\/td>\n<td>350<\/td>\n<td>800<\/td>\n<td>250<\/td>\n<td>500<\/td>\n<td>1500<\/td>\n<\/tr>\n<tr>\n<td>\u4e3b\u8981\u7ed3\u6784\u7279\u5f81<\/td>\n<td>EO-PO\u5d4c\u6bb5<\/td>\n<td>\u6c28\u57fa\u6539\u6027<\/td>\n<td>\u73af\u6c27\u57fa\u63a5\u679d<\/td>\n<td>\u53cc\u7aef\u7f9f\u57fa<\/td>\n<td>\u805a\u919a-\u7845\u6c27\u70f7\u661f\u578b<\/td>\n<td>\u542b\u6c1f\u70f7\u57fa\u4fa7\u94fe<\/td>\n<\/tr>\n<tr>\n<td>\u5e73\u5747\u5206\u5b50\u91cf (g\/mol)<\/td>\n<td>4200<\/td>\n<td>5800<\/td>\n<td>6500<\/td>\n<td>3800<\/td>\n<td>7200<\/td>\n<td>8600<\/td>\n<\/tr>\n<tr>\n<td>\u8868\u9762\u5f20\u529b (mN\/m, 25\u2103)<\/td>\n<td>21.2<\/td>\n<td>20.8<\/td>\n<td>20.5<\/td>\n<td>21.5<\/td>\n<td>20.3<\/td>\n<td>19.7<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u5206 (150\u2103, 2h, wt%)<\/td>\n<td>0.15<\/td>\n<td>0.12<\/td>\n<td>0.09<\/td>\n<td>0.18<\/td>\n<td>0.07<\/td>\n<td>0.05<\/td>\n<\/tr>\n<tr>\n<td>D4\u542b\u91cf (ppm)<\/td>\n<td>\uff1c80<\/td>\n<td>\uff1c60<\/td>\n<td>\uff1c50<\/td>\n<td>\uff1c100<\/td>\n<td>\uff1c40<\/td>\n<td>\uff1c30<\/td>\n<\/tr>\n<tr>\n<td>Cl\u207b\u542b\u91cf (ppm)<\/td>\n<td>3.2<\/td>\n<td>2.8<\/td>\n<td>2.1<\/td>\n<td>4.5<\/td>\n<td>1.9<\/td>\n<td>1.5<\/td>\n<\/tr>\n<tr>\n<td>Na\u207a\u542b\u91cf (ppm)<\/td>\n<td>1.7<\/td>\n<td>1.5<\/td>\n<td>1.3<\/td>\n<td>2.0<\/td>\n<td>1.2<\/td>\n<td>0.9<\/td>\n<\/tr>\n<tr>\n<td>\u63a8\u8350\u6dfb\u52a0\u91cf (phr)<\/td>\n<td>0.2\u20130.5<\/td>\n<td>0.3\u20130.6<\/td>\n<td>0.4\u20130.7<\/td>\n<td>0.2\u20130.4<\/td>\n<td>0.3\u20130.5<\/td>\n<td>0.5\u20130.8<\/td>\n<\/tr>\n<tr>\n<td>\u4f73\u9002\u914d\u591a\u5143\u9187\u7c7b\u578b<\/td>\n<td>\u805a\u919a\uff08POP\uff09<\/td>\n<td>\u805a\u916f\uff08PBA\uff09<\/td>\n<td>\u805a\u919a\uff08PPG\uff09<\/td>\n<td>\u805a\u919a\uff08PTMG\uff09<\/td>\n<td>\u805a\u919a\uff08POP\/PPG\u6df7\u5408\uff09<\/td>\n<td>\u9ad8\u6781\u6027\u805a\u916f<\/td>\n<\/tr>\n<tr>\n<td>\u5178\u578b\u5e94\u7528\u4ea7\u54c1<\/td>\n<td>\u624b\u673a\u542c\u7b52\u57ab<\/td>\n<td>\u6298\u53e0\u5c4f\u94f0\u94fe\u57ab<\/td>\n<td>TWS\u8033\u673a\u58f0\u57ab<\/td>\n<td>\u667a\u80fd\u624b\u8868\u4f20\u611f\u5668\u57ab<\/td>\n<td>AR\u773c\u955c\u9f3b\u6258\u57ab<\/td>\n<td>\u8f66\u8f7d\u4e2d\u63a7\u5c4f\u7f13\u51b2\u57ab<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4f7f\u7528\u63d0\u793a\uff1a<br \/>\n\u2022 \u578b\u53f7A\u3001D\u9002\u7528\u4e8e\u4f4e\u786c\u5ea6\uff08Shore A 10\u201315\uff09\u3001\u9ad8\u56de\u5f39\uff08\uff1e95%\uff09\u7684\u8584\u578b\u57ab\u7247\uff08\u539a\u5ea6\u22640.3 mm\uff09\uff0c\u56e0\u5176\u4f4e\u7c98\u5ea6\u5229\u4e8e\u5feb\u901f\u5206\u6563\uff0c\u4e14\u53cc\u7aef\u7f9f\u57fa\u53ef\u53c2\u4e0e\u4ea4\u8054\uff0c\u63d0\u5347\u7f51\u7edc\u5bc6\u5ea6\uff1b<br \/>\n\u2022 \u578b\u53f7B\u3001C\u5bf9\u805a\u916f\u591a\u5143\u9187\u4f53\u7cfb\u76f8\u5bb9\u6027\u6781\u4f73\uff0c\u7279\u522b\u9002\u5408\u9700\u8010\u6c57\u6db2\u3001\u8010\u6cb9\u8102\u7684\u53ef\u7a7f\u6234\u8bbe\u5907\u57ab\u7247\uff0c\u6c28\u57fa\/\u73af\u6c27\u57fa\u53ef\u4e0e\u7fa7\u57fa\u53d1\u751f\u5f31\u53cd\u5e94\uff0c\u6291\u5236\u9ad8\u6e29\u4e0b\u8f6f\u6bb5\u8fc1\u79fb\uff1b<br \/>\n\u2022 \u578b\u53f7E\u3001F\u5206\u5b50\u91cf\u5927\u3001\u6325\u53d1\u5206\u6781\u4f4e\uff0c\u9002\u7528\u4e8e\u957f\u5468\u671f\u8fde\u7eed\u5316\u751f\u4ea7\uff08\u5982\u81ea\u52a8\u5316\u704c\u80f6\u7ebf\uff09\uff0c\u51cf\u5c11\u8bbe\u5907\u7ba1\u8def\u6c89\u79ef\u4e0e\u771f\u7a7a\u6cf5\u6cb9\u6c61\u67d3\u98ce\u9669\uff1b<br \/>\n\u2022 \u6240\u6709\u578b\u53f7\u5747\u987b\u5728PU\u9884\u805a\u4f53\u6e29\u5ea6\u964d\u81f370\u201380\u2103\u540e\u518d\u52a0\u5165\uff0c\u907f\u514d\u9ad8\u6e29\u4e0b\u7845\u6cb9\u964d\u89e3\u4ea7\u751f\u6c14\u6ce1\uff1b\u6405\u62cc\u901f\u5ea6\u5b9c\u63a7\u5236\u5728200\u2013300 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